Stackability varies by deal. The fine print section of any deal page will let you know if the voucher is limited one per order or stackable. 

Collage percentage-off vouchers/sales, such as the 50% off first-time buyer discount, cannot be combined with other vouchers, coupons, promotions, or gift cards (including vouchers from Groupon or LivingSocial).

You cannot use a voucher to purchase another deal. Vouchers are only valid toward regular priced print products.  

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